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Abstract The Zintl compound TlInTe₂is an intriguing material because of its outstanding thermoelectric properties at ambient pressure. Interestingly, it has recently been found that TlInTe₂exhibits a V-shape dependence of the superconducting critical temperature (T_c) under increasing pressure, which has been linked to the reversed behavior of the Raman active A_gphonon mode and anharmonic effects. In this study, we have performed first-principles calculations of the electron-phonon interactions and the superconducting properties of TlInTe₂in order to understand this unusual pressure-induced response. In contrast to experiment, we find a dome-shaped pressure-induced dependence ofT_cwith a maximum value of 0.23 K at 18 GPa, significantly lower than the experimental results. Electron doping has the potential to adjust theT_cto fall within the experimental range, but it necessitates considerably high levels of doping. Furthermore, our analysis of the phonon spectra and phonon lifetimes, including anharmonic effects, show that anharmonicity is unlikely to influence the superconducting properties of TlInTe₂. It remains an open question whether there is indeed an unusual V-shapeT_cdependence with pressure or whether the phonon-mediated theory of superconductivity used here breaks down in this system. 

We use frequency domain holography (FDH) to spatio-temporally visualize the laser-matter interaction caused by the optical Kerr effect and plasma in flexible Corning® Willow® Glass in a single-shot. 

We measure the nonlinear index of refraction (n2) and investigate plasma dynamics in flexible Corning® Willow® Glass using single-shot Frequency Domain Holography (FDH). Flexible glass has received a lot of attention recently due to various applications such as 3-D photonics and wearable devices. Femtosecond laser micromachining (FLM) is a viable tool to fabricate these devices because of minimal thermal effects and thus enables fabrication of small and clean 3-D structures. To control and understand the underlying dynamics of FLM, ultrafast visualization of plasma and optical Kerr effect is important. FDH is a robust femtosecond time-resolved technique in which chirped reference and probe pulses centered at 404 nm are used to measure and visualize the plasma and Kerr effect produced by an intense, ultrashort pump pulse centered at 808 nm. Using FDH, we study laser-matter interactions in Willow Glass and measure its n2 to be 3.41 +/-0.08 ×10-16 cm2/W and visualize the plasma dynamics.